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Name and surname:
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Mgr. Peter Hrobárik, PhD.
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Document type:
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Research/art/teacher profile of a person
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The name of the university:
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Comenius University Bratislava
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The seat of the university:
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Šafárikovo námestie 6, 818 06 Bratislava
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| III.a - Occupation-position | III.b - Institution | III.c - Duration |
|---|---|---|
| associate professor | Faculty of Natural Sciences, Comenius University in Bratislava | 2025-present |
| assistant professor | Faculty of Natural Sciences, Comenius University in Bratislava | 2017 -2025 |
| senior researcher | Technical University of Berlin, Germany | 2011-2017 |
| senior researcher | Julius-Maximilians University Würzburg, Germany | 2009-2010 |
| researcher | Institute of Inorganic Chemistry, Slovak Academy of Sciences | 2004-2009 |
| V.1.a - Name of the profile course | V.1.b - Study programme | V.1.c - Degree | V.1.d - Field of study |
|---|---|---|---|
| General and Inorganic Chemistry | Biological chemistry (interfield biology-chemistry) | I. | Biology |
| Perspektívy chémie | Chémia | I. | Chemistry |
| Advanced main group chemistry and applications | Inorganic chemistry | II. | Chemistry |
| Chémia neprechodných prvkov | Inorganic chemistry | II. | Chemistry |
| Fotochemické procesy | Inorganic chemistry | II. | Chemistry |
| Metódy charakterizácie anorganických látok a materiálov 1 | Inorganic chemistry | II. | Chemistry |
| Chémia prechodných prvkov | Inorganic chemistry | II. | Chemistry |
| Materials photochemistry | Chemistry | II. | Chemistry |
| Molecular modeling | Chemistry | II. | Chemistry |
| V.5.a - Name of the course | V.5.b - Study programme | V.5.c - Degree | V.5.d - Field of study |
|---|---|---|---|
| Bakalárska práca z anorganickej chémie | Chemistry | I. | Chemistry |
| Seminár k diplomovej práci | Chemistry | II. | Chemistry |
| Cvičenie diplomantov | Inorganic Chemistry | II. | Chemistry |
| Doktorandský seminár z anorganickej chémie | Inorganic Chemistry | III. | Chemistry |
| Vybrané kapitoly z koordinačnej chémie | Inorganic Chemistry | I.+II. | Chemistry |
ADC Hrobáriková, V.; Hrobárik, P.;* Gajdoš, P.; Fitilis, I.; Fakis, M.; Persephonis, P.; Zahradník, P. "Benzothiazole-Based Fluorophores of Donor-pi-Acceptor-pi-Donor Type Displaying High Two-Photon Absorption" J. Org. Chem. 2010, 75, 3053-3068 (SCI citations 149)
ADC Hrobárik, P.;* Hrobáriková, V.; Sigmundová, I.; Zahradník, P.; Fakis, M.; Polyzos, I.; Persephonis, P. "Benzothiazoles with Tunable Electron-Withdrawing Strength and Reverse Polarity: A Route to Triphenylamine-Based Chromophores with Enhanced Two-Photon Absorption" J. Org. Chem. 2011, 76, 8726-8736 (SCI citations 140)
ADC Hrobárik, P.;* Hrobáriková, V.; Meier, F.; Repiský, M.; Komorovský, S.; Kaupp, M.* "Relativistic Four-Component DFT Calculations of 1H NMR Chemical Shifts in Transition-Metal Hydride Complexes: Unusual High-Field Shifts Beyond the Buckingham-Stephens Model" J. Phys. Chem. A 2011, 115, 5654-5659 (SCI citations 118)
ADC Smiles, D. E.; Wu, G.; Hrobárik, P.;* Hayton, T. W.* "Use of 77Se and 125Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(En){N(SiMe3)2}3]- (E = Se, Te; n=1, 2) and Their Oxo-Uranium(VI) Congeners" J. Am. Chem. Soc. 2015, 138, 814-825 (SCI citations 112)
ADC Hrobárik, P.;* Sigmundová, I.; Zahradník, P.; Kasák, P.; Arion, V.; Franz, E.; Clays, K. "Molecular Engineering of Benzothiazolium Salts with Large Quadratic Hyperpolarizabilities: Can Auxiliary Electron-Withdrawing Groups Enhance Nonlinear Optical Responses?" J. Phys. Chem. C 2010, 114, 22289-22302 (SCI citations 110)
ADC Osuský, P.; Nociarová, J.; Smolíček, M.; Gyepes, R.; Georgiou, D.; Polyzos, I.; Fakis, M.; Hrobárik, P.* "Oxidative C‐ H Homocoupling of Push‐ Pull Benzothiazoles: An Atom-Economical Route to Highly Emissive Quadrupolar Arylamine‐Functionalized 2,2’‐Bibenzothiazoles with Enhanced Two‐Photon Absorption", Org. Lett. 2021, 23, 5512-5517 (SCI citations 27)
ADC Henkelmann, M.; Omlor, A.; Bolte, M.; Schünemann, V.; Lerner, H.-W.; Noga, J.; Hrobárik, P.;* Wagner, M.* "A Free Boratriptycene-Type Lewis Superacid", Chem. Sci. 2022, 13, 1608–1617 (SCI citations 26)
ADC Nociarová, J.; Osuský, P.; Rakovský, E.; Georgiou, D.; Polyzos, I.; Fakis, M.; Hrobárik, P.* "Direct Iodination of Electron-Deficient Benzothiazoles: Rapid Access to Two-Photon Absorbing Fluorophores with Quadrupolar D-pi-A-pi-D Architecture and Tunable Heteroaromatic Core", Org. Lett. 2021, 23, 3460–3465 (SCI citations 25)
ADC Osuský, P.; Smolíček, M.; Nociarová, J.; Rakovský, E.; Hrobárik, P.* "One-Pot Reductive Methylation of Nitro- and Amino-Substituted (Hetero)Aromatics with DMSO/HCOOH: Concise Synthesis of Fluorescent Dimethylamino-Functionalized Bibenzothiazole Ligands with Tunable Emission Color upon Complexation", J. Org. Chem. 2022, 87, 10613–10629 (SCI citations 14)
ADC Nociarová, J.; Purkait, A.; Gyepes, R.; Hrobárik, P.* "Silver-Catalyzed Skeletal Editing of Benzothiazol-2(3H)-ones and 2-Halogen-Substituted Benzothiazoles as a Rapid Single-Step Approach to Benzo[1,2,3]Thiadiazoles", Org. Lett. 2024, 26, 619–624 (SCI citations 8)
ADC Hrobáriková, V.; Hrobárik, P.;* Gajdoš, P.; Fitilis, I.; Fakis, M.; Persephonis, P.; Zahradník, P. "Benzothiazole-Based Fluorophores of Donor-pi-Acceptor-pi-Donor Type Displaying High Two-Photon Absorption" J. Org. Chem. 2010, 75, 3053-3068 (SCI citácie 149)
vysokocitovaná práca v oblasti materiálovej chémie a syntézy NLO-aktívnych farbív
príklad ohlasu:
Xu, B. J.; Xie, M. Y.; He, J. J. et al. "An aggregation-induced emission luminophore with multi-stimuli single- and two-photon fluorescence switching and large two-photon absorption cross section", Chem. Commun. 2013, 49, 273-275
ADC Hrobárik, P.;* Hrobáriková, V.; Sigmundová, I.; Zahradník, P.; Fakis, M.; Polyzos, I.; Persephonis, P. "Benzothiazoles with Tunable Electron-Withdrawing Strength and Reverse Polarity: A Route to Triphenylamine-Based Chromophores with Enhanced Two-Photon Absorption" J. Org. Chem. 2011, 76, 8726-8736 (SCI citácie 140)
vysokocitovaná práca v oblasti materiálovej chémie a syntézy trifenylamínových farbív
príklad ohlasu:
Kundu, B. K.; Han, G. Q.; Sun, Y. J. "Derivatized Benzothiazoles as Two-Photon-Absorbing Organic Photosensitizers Active under Near Infrared Light Irradiation", J. Am. Chem. Soc. 2023, 145, 3535−3542
ADC Smiles, D. E.; Wu, G.; Hrobárik, P.;* Hayton, T. W.* "Use of 77Se and 125Te NMR Spectroscopy to Probe Covalency of the Actinide-Chalcogen Bonding in [Th(En){N(SiMe3)2}3]- (E = Se, Te; n=1, 2) and Their Oxo-Uranium(VI) Congeners" J. Am. Chem. Soc. 2016, 138, 814-825 (SCI citácie 112)
práca citovaná vo vysokoimpaktových časopisoch pri stanovovaní kovalentnosti väzieb v komplexných zlúčeninách aktinoidov pomocou NMR spektroskopie
príklad ohlasu:
Du, J. Z.; Seed, J. A.; Berryman, V. E. J. et al. "Exceptional uranium(VI)-nitride triple bond covalency from 15N nuclear magnetic resonance spectroscopy and quantum chemical analysis", Nature Comm. 2021, 12, 5649
ADC Hrobárik, P.;* Hrobáriková, V.; Greif, A. H.; Kaupp, M. "Giant Spin-Orbit Effects on NMR Shifts in Diamagnetic Actinide Complexes: Guiding the Search of Uranium(VI) Hydride Complexes in the Correct Spectral Range", Angew. Chem. Int. Ed. 2012, 51, 10884-10888 (SCI citácie 85)
práca citovaná v oblasti NMR charakterizácie komplexných zlúčenín ťažkých kovov vo vysokoimpaktových časopisoch ako JACS, ACIE, Nature Comm, PNAS
príklad ohlasu:
Baker, C. F.; Davis, M.; Seed, J. A. et al. "M=CR2 (M = U, Y) Diphosphonioalkylidene and U≡O Terminal Oxo Multiple Bond Interactions Encoded in 13C and 17O Nuclear Magnetic Resonance Chemical Shift Anisotropies: Correlations of M=C Bond Order to Chemical Shift Tensors", J. Am. Chem. Soc. 2026, 148, 27466-27483
ADC Rocchigiani, L.;* Fernandez-Cestau, J.; Chambrier, I.; Hrobárik, P.;* Bochmann, M.* "Unlocking Structural Diversity in Gold(III) Hydrides: Unexpected Interplay of cis/trans -Influence on Stability, Insertion Chemistry and NMR Chemical Shifts" J. Am. Chem. Soc. 2018, 140, 8287-8302 (SCI citácie 60)
práca citovaná vo vysokoimpaktových časopisoch ohľadom charakterizácie hydridov prechodných kovov a katalytickej aktivity zlúčenín zlata
príklad ohlasu:
Herrera, R. P.; Gimeno, M. C. "Main Avenues in Gold Coordination Chemistry", Chem. Rev. 2021, 121, 8311-8363
Principal Investigator: 09I03-03-V03-00040, Large Projects for Excellent Researchers, NextGenerationEU, "Pushing Boundaries in Molecular Materials by Combining Various Functionalities (PUSHMAT)" (2024-2026)
Principal Investigator: APVV-21-0503 "Small-Molecular Luminescent Probes and Photosensitizers for Two-Photon Excited Bioimaging and Anti-Infective Treatment" (2022-2026)
Principal Investigator: VEGA 1/0669/22 "Highly efficient triplet photosensitizers for photodynamic therapy and phosphorescent imaging" (2022-2025)
Investigator: APVV-22-0150 "Photofunctional Hybrid Materials of Organic Luminophores and Nanoparticles of Layered Silicates" (2023-2027)
Investigator: 810701 — LAMatCU — H2020-WIDESPREAD-2016-2017/H2020-WIDESPREAD-03-2017-ERAChairs, "Establishing Laboratory of Advanced Materials" at the Comenius University (2018-2024)
| VIII.a - Name of the institution | VIII.b - Address of the institution | VIII.c - Duration (indicate the duration of stay) | VIII.d - Mobility scheme, employment contract, other (describe) |
|---|---|---|---|
| Technische Universität Berlin | Berlin, Germany | 2011-2017 | pracovný kontrakt |
| Julius Maximilians Universität Würzburg | Würzburg, Germany | 2009-2010 | štipendium A. von Humboldta |
| Radboud University in Nijmengen | Nijmengen, Netherlands | 2008 (2 months) | výskumný pobyt |
| Forschungszentrum Karlsruhe | Karlsruhe, Germany | 2007 (2 months) | výskumný pobyt |
| University of Helsinki | Helsinki, Finland | 2006 (2 months) | výskumný pobyt |
| École Polytechnique Fédérale de Lausanne | Lausanne, Switzerland | 2005 (2 months) | výskumný pobyt |
| Göthe-Universität Frankfurt | Frankfurt, Germany | 2004 (3 months) | výskumný pobyt |
| Julius Maximilians Universität Würzburg | Würzburg, Germany | 2003-2008 (9 months) | výskumný pobyt |
| Karl-Franzens-Universität Graz | Graz, Austria | 2003 (3 months) | CEEPUS štipendium |